Effect of Cross-linking Systems on the Thermal Behaviour of Nylon Copolymer (PA6,66) and Ethylene-Propylene-Diene (EPDM) Rubber Blends and their Kinetic Analysis

##plugins.themes.academic_pro.article.main##

Cibi Komalan
K. E. George
S. Thomas
K. T. Varughese

Abstract

The thermal stability of nylon 6,66 and ethylene-propylene-diene rubber of dynamically vulcanised blends were studied by thermogravimetric analysis. The composition of nylon copolymer and EPDM was fixed at 70/30 ratio by weight. The blends were prepared by melt mixing in a Brabender Plasticorder. Thermogravimetric analysis showed that the decomposition proceeds through a single step even though the blends are immiscible and the cross-linked blends were more thermally stable than uncross-linked blends. The kinetic parameter of the degradation process is also studied.

##plugins.themes.academic_pro.article.details##

How to Cite
Komalan, C., George, K. E., Thomas, S., & Varughese, K. T. (2008). Effect of Cross-linking Systems on the Thermal Behaviour of Nylon Copolymer (PA6,66) and Ethylene-Propylene-Diene (EPDM) Rubber Blends and their Kinetic Analysis. Power Research - A Journal of CPRI, 175–178. Retrieved from https://node6473.myfcloud.com/~geosocin/CPRI/index.php/pr/article/view/974

References

  1. Varkey J T, Augustine S, Thomas S, Polym. Plast. Technol. And Eng., 39, 415, 2000.
  2. Mathew A P, Packirisamy S, Thomas S, Polym. Degrad. Stab., 72, pp. 423, 2000.
  3. Stack S, O'Donogbue O, Birkinshaw C, Polym. Degrad. Stab., 79, 29, 2003.
  4. Vrandeéie N S, Klariez I, Kovaéie T, Polym. Degrad. Stab., 84, 23, 2004.
  5. Pesetskii S S, Olkhov Y A, Bagdanovich S P, Koval VN, Euro. Polym., J, 41, 1380, 2005.
  6. Roeder J, Oliveira R U B, Becker D, Goncalves M W, Soldi V, Pires A TN, Polym. Degrad. Stab., 90, 481, 2006.
  7. Souza J L, Santos A F, Ribeiro C A, Ther. Ana. and Calorimetry, 87, 673, 2007.
  8. Joshi R, Leferre E, Patal C, Provder T, Crombez R, J. Ther. Ana. and Calorimetry, 93, 19, 2008.
  9. Waldman W R, De Paoli A, Polym. Degrad. Stab., 93, 273, 2008.
  10. Chen H, Hu X, P. Cebe. Ther. Ana. and Calorimetry , 93, 201, 2008.
  11. Huang H, Yang J, Liu X, Zhang Y, Euro. Polym. J., 38, 857, 2002.
  12. Coats A W, Redfern, Nature J.P, 68, 201, 1964.
  13. Satara V. Thermo. Chem. Acta., 2, 423, 1971.

Similar Articles

1 2 3 > >> 

You may also start an advanced similarity search for this article.